| 室温离子液体[HMIM]BF4中8种1,3-二硫杂环己烷类化合物的合成 |
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| 引用本文： | 徐晓东,郑福平,孙宝国,谢建春,田红玉,刘玉平,李宁.室温离子液体[HMIM]BF4中8种1,3-二硫杂环己烷类化合物的合成[J].食品科技,2006,31(9):158-161. |
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| 作者姓名： | 徐晓东 郑福平 孙宝国 谢建春 田红玉 刘玉平 李宁 |
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| 作者单位： | 北京工商大学化学与环境工程学院,北京,100037 |
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| 摘 要： | 以室温离子液体N-甲基咪唑四氟硼酸盐(HMIM]BF4)作溶剂和催化剂,1,3-丙二硫醇分别和醛、酮反应制得8种1,3-二硫环己烷类香料化合物.采用元素分析、红外光谱、氢核磁共振、色-质联机对产品进行了结构表征,并作了香气评价.
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| 关 键 词： | 室温离子液体 1 3-二硫环己烷 香料 合成 |
| 文章编号： | 1005-9989(2006)09-0158-03 |
| 修稿时间： | 2006年5月7日 |
Syntheses of eight 1,3-dithiolanein in room temperature ionic liquid [HMIM]BF4 |
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| XU Xiao-dong,ZHENG Fu-ping,SUN Bao-guo,XIE Jian-chun,TIAN Yu-hong,LIU ping-Yu,LI Ning.Syntheses of eight 1,3-dithiolanein in room temperature ionic liquid [HMIM]BF4[J].Food Science and Technology,2006,31(9):158-161. |
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| Authors: | XU Xiao-dong ZHENG Fu-ping SUN Bao-guo XIE Jian-chun TIAN Yu-hong LIU ping-Yu LI Ning |
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| Abstract: | Eight 1,3-dithiolane were synthesized by the reaction of aldehyde or ketone with 1,3-dimercaprol in room temperature ionic liquid 1-methylimidazolium tetrafluoroborate (HMIMBF4). Structure of the target compounds was identified by data of elemental analysis, FTIR, 1H NMR and GC-MS. and contents the studying of the properties of those flavoring compounds. The odor characteristics of the eight 1,3-dithiolane were evaluated. |
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| Keywords: | [HMIM]BF4 |
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