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合成氨工业废水高效短程生物脱氮中试研究
引用本文:李泽兵, 马家轩, 王晓毅, 李妍, 赵白航, 李军. 合成氨工业废水高效短程生物脱氮中试研究[J]. 北京工业大学学报, 2012, 38(9): 1436-1440.
作者姓名:李泽兵  马家轩  王晓毅  李妍  赵白航  李军
作者单位:1. 北京工业大学建筑工程学院,北京,100124
2. 河南省化工研究所有限责任公司,郑州,450052
基金项目:国家重大水专项资助项目
摘    要:以某实际合成氨化工厂废水为研究对象,进行高氨氮化工废水缺氧/好氧(A/O)工艺高效短程生物脱氮中试研究.试验结果表明:A/O系统经过90 d的运行,实现了稳定的短程硝化,并获得了稳定的有机物和氮去除.亚硝态氮积累率维持在80%以上,COD、NH4+-N和TN的去除率分别达到了95%、99%和80%.此外,机理分析表明,A/O中试系统获得稳定短程硝化的主要因素为较低ρ(DO)、较高ρ(FA)及适宜HRT三者的协同调控.

关 键 词:合成氨工业  A/O工艺  短程硝化反硝化  游离氨
收稿时间:2011-02-27

Pilot Study on Shortcut Biological Nitrogen Removal With Synthetic Ammonia Industrial Wastewater
LI Ze-bing, MA Jia-xuan, WANG Xiao-yi, LI Yan, ZHAO Bai-hang, LI Jun. Pilot Study on Shortcut Biological Nitrogen Removal With Synthetic Ammonia Industrial Wastewater[J]. Journal of Beijing University of Technology, 2012, 38(9): 1436-1440.
Authors:LI Ze-bing  MA Jia-xuan  WANG Xiao-yi  LI Yan  ZHAO Bai-hang  LI Jun
Affiliation:1(1.College of Civil Engineering and Architecture,Beijing University of Technology,Beijing 100124,China; 2.Henan Chemical Industry Research Institute Co.Ltd,Zhengzhou 450052,China)
Abstract:A pilot-scale study on shortcut biological nitrogen removal from synthetic ammonia industrial wastewater was researched in an aerobic-anoxic system.The industrial wastewater contained a high NH4+-N concentration with 80-110 mg/L.Experimental results showed that a stable short-cut nitrification and denitrification was achived after a period of 90 d operation.The accumulation nitrite was keeping above 80%.The removal efficiencies of COD、NH4+-N and TN was 95%,99% and 80%,respectively.In addition,the mechanism analysis showed that the main reason for getting the stable short-cut nitrification and denitrification in the pilot system was attributed to the collaboration of low dissolved oxygen(DO),high free ammonia(FA) and appropriate hydraulic retention time(HRT).
Keywords:synthetic ammonia industria  A/O process  short-cut nitrification and denitrification  free ammonia
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