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Control of nano-sized interlayer space of lamellar vanadyl benzylphosphate
Authors:Atsushi Satsuma  Hironaka Kanbe  Kannan Srinivasan  Shin-ich Komai  Yuichi Kamiya  Tadashi Hattori
Affiliation:

aGraduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan

bSilicates and Catalysis Discipline, Central Salt and Marine Chemicals Research Institute, Bhavnagar-364 002, India

cResearch Faculty of Environmental Earth Science, Hokkaido University, Sapporo 060-0810, Japan

Abstract:Nano-sized interlayer space of lamellar vanadyl benzylphosphate was controlled by water content in starting solution. Depending on the water content, three types of lamellar vanadyl benzylphosphate having basal spacings of 1.4 nm, 1.9 nm and 2.3 nm were obtained. It was suggested that the difference in the concentrations of benzyl and hydroxyl groups in the interlayer leads to the variation of the interlayer space.
Keywords:Vanadyl benzylphosphate  Intercalation  Lamellar compound  Interlayer Space  Hydroxyl group
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