Magnetic Properties of Mechanically Alloyed Cobalt-Zinc Ferrite Nanoparticles

In this work, the physical and the magnetic properties of cobalt-zinc ferrite nanoparticles, synthesized via high-energy ball milling (HEBM), were examined. X-Ray diffraction (XRD), field emission scanning electron microscopy (FeSEM), and scanning transmission electron microscopy (STEM) were used to study changes of the powder structure and morphology analyses. Hysteresis and permeability measurement were carried out using a BH hysteresisgraph system and an impedance analyzer, respectively. The results suggested improved magnetic properties of Co_0.5Zn_0.5Fe₂O₄ with increasing sintering temperature from 950 °C up to 1200 °C. However, the variations of the magnetic responses were consistent with the varying volume concentration of the ferrite composites. Unlike the highly crystalline pure ferrite which showed magnetic resonance within the measured frequency, the crystallineamorphous composites showed no visible resonance peak. This proved that the resonance peak shifted to higher frequency as a result of the single domain spin behavior in the absence of domain walls movement.