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反应火焰喷涂TiC/Fe复合涂层的动力学
引用本文:刘长松,李志文,黄继华,殷声.反应火焰喷涂TiC/Fe复合涂层的动力学[J].中国有色金属学报,2006,16(9):1522-1526.
作者姓名:刘长松  李志文  黄继华  殷声
作者单位:1. 青岛理工大学,机械工程学院,青岛,266033;北京科技大学,材料科学与工程学院,北京,100083
2. 青岛理工大学,机械工程学院,青岛,266033
3. 北京科技大学,材料科学与工程学院,北京,100083
基金项目:山东省青岛市科技发展基金;河南省高校杰出科研创新人才工程项目
摘    要:以钛铁、铁和石墨为主要原料,用反应火焰喷涂技术制备TiC/Fe复合涂层。在喷涂过程中,在氧乙炔火焰条件下引燃Fe-Ti-C体系的自蔓延高温合成(SHS)反应,研究该SHS反应的动力学。结果表明,适当增加铁和石墨,或减小反应组元的粒度,会显著降低体系的点火温度,可促进Fe-Ti-C反应体系在氧乙炔火焰中的点火进程。喷涂粉末粒度、氧乙炔火焰功率、喷涂距离以及喷涂粉末的原料配比均会影响Ti-C间的反应程度,从而影响Fe-Ti-C体系的反应动力学。

关 键 词:自蔓延高温合成  反应动力学  TiC/Fe涂层  氧乙炔火焰  热喷涂
文章编号:1004-0609(2006)09-1522-05
收稿时间:2006-03-13
修稿时间:2006-07-15

Dynamics of reactive flame sprayed TiC/Fe composite coatings
LIU Chang-song,LI Zhi-wen,HUANG Ji-hua,YIN Sheng.Dynamics of reactive flame sprayed TiC/Fe composite coatings[J].The Chinese Journal of Nonferrous Metals,2006,16(9):1522-1526.
Authors:LIU Chang-song  LI Zhi-wen  HUANG Ji-hua  YIN Sheng
Affiliation:1. School of Mechanical Engineering, Qingdao Technological University, Qingdao 266033, China;2. School of Materials Science and Technology, University of Science and Technology Beijing, Beijing 100083, China
Abstract:The TiC/Fe composite coatings were prepared by reactive flame spray using ferrotitanium,iron and graphite as the starting materials,which need ignite the self-propagation high-temperature synthesis(SHS) reaction of Fe-Ti-C system by oxygen-acetylene flame.The dynamics of this SHS reaction were studied.The ignition temperature is reduced by increasing Fe content and graphite content or by decreasing the size of reactive components.The degree of the complete reaction is affected by spray powder size,oxygen-acetylene flame power,spray distance and the composition of spray powder.
Keywords:self-propagation high-temperature synthesis  reaction dynamics  TiC/Fe coatings  oxygen-(acetylene) flame  thermal spray
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