A multiple-scattering model analysis of zinc oxide pigment for spacecraft thermal control coatings

Space assets inhabit a harsh thermal environment in which the high intensity of direct solar radiation can potentially raise temperatures to harmful levels. Thermal management is obtained through the use of radiators coated with thermal control coatings (TCCs) that diffusely reflect the sun’s high energy visible (VIS) and near infrared (NIR) radiation, while emitting infrared (IR) energy as a method of radiatively cooling. The current state-of-the-art TCC system utilizes a potassium silicate binder and zinc oxide (ZnO) pigment to maintain solar reflectance over a long exposure time. We are investigating improvements to TCCs that will have greater initial performance and significantly better end-of-life properties. We have utilized modeling techniques based upon Mie scattering to determine the theoretical scattering efficiency limits of the currently used materials. An optimized TCC would attain maximum diffuse solar reflectance at a lower film thickness and reduce the pigment volume concentration (PVC) required. These factors would contribute to a reduction in overall weight and possibly extend the durability of the system to longer time scales. Our results of modeling ZnO pigment embedded in a matrix similar to that of potassium silicate under solar irradiance conditions indicate that a narrow particle size distribution centered at 0.35 μm would provide the highest overall scattering coefficients, ranging from 0.75 μm⁻¹ at 1000 nm to 5.0 μm⁻¹ at 380 nm wavelengths. These results indicated that a significant improvement, 2–10 times dependent upon wavelength, in the scattering efficiency of ZnO-based TCCs can be realized by utilizing an optimized particle size distribution rather than the currently used size distribution.