| 松木粉制备高比表面积炭基固体酸催化剂 |
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| 引用本文： | 张文娟,马海龙,杨亚提,张增强,高锦明.松木粉制备高比表面积炭基固体酸催化剂[J].林产化工通讯,2012(1):15-18. |
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| 作者姓名： | 张文娟 马海龙 杨亚提 张增强 高锦明 |
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| 作者单位： | [1]西北农林科技大学资源环境学院,陕西杨凌712100 [2]陕西省资源化学与可持续利用工程研究中心；西北农林科技大学理学院,陕西杨凌712100 [3]煤转化国家重点实验室；中国科学院山西煤炭化学研究所,山西太原030001 |
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| 基金项目： | 煤转化国家重点实验室开放基金项且（10一11-905）;西北农林科技大学基本科研业务费青年项目（QN2009050） |
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| 摘 要： | 以一种廉价的农林废弃物——松木粉为原料,首先经过炭化和活化处理,制备活性炭,再通过苯磺酸重氮盐还原法处理活性炭引入磺酸基团（—SO3H）,从而制备出具有高比表面积的炭基固体酸催化剂（AC-SO3H）。其比表面积达到1364 m2/g,磺酸基密度为1.36 mmol/g。以乙酸的酯化反应考察了炭基固体酸催化剂的催化活性,并与Amberlyst-15、Nafion NR50以及Nafion SAC-13等几种固体酸催化剂进行了比较。实验结果表明,炭基固体酸催化剂的催化活性仅略低于Amberlyst-15,高于Nafion NR50和Nafion SAC-13,炭基固体酸催化剂的成本也远远低于Nafion NR50和NafionSAC-13。研究结果表明,以松木粉为原料,通过炭化、活化和磺化处理能够得到性能优异且成本低廉的炭基固体酸催化剂。
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| 关 键 词： | 松木粉 高比表面 炭基固体酸 催化剂 |
Preparation of a Carbon-based Solid Acid Catalyst with High Specific Surface Area from Pine Wood Powder |
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| ZHANG Wen-juan,MA Hai-long,YANG Ya-ti,ZHANG Zeng-qiang,GAO Jin-ming.Preparation of a Carbon-based Solid Acid Catalyst with High Specific Surface Area from Pine Wood Powder[J].Journal of Chemical Industry of Forest Products,2012(1):15-18. |
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| Authors: | ZHANG Wen-juan MA Hai-long YANG Ya-ti ZHANG Zeng-qiang GAO Jin-ming |
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| Affiliation: | 1.College of Resources and Environment,Northwest A ＆ F University,Yangling 712100,China;2.Shaanxi Engineering Center of Bioresource Chemistry ＆ Sustainable Utilization;College of Science,Northwest A ＆ F University,Yangling 712100,China; 3.State Key Laboratory of Coal Conversion,Institute of Coal Chemistry,CAS,Taiyuan 030001,China) |
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| Abstract: | A sulfonated（SO3H-bearing） Carbon-based solid acid catalyst was prepared from pine wood powder — a cheap forest waste.The catalyst was obtained by the carbonization,activation and sulfonation of pine wood powder.The specific surface area and SO3H density of the carbon catalyst were 1364 m2/g and 1.36 mmol/g,respectively.The catalytic activity of carbon catalyst was investigated on the acetic acid esterification reaction and compared with that of several commercial solid acid catalysts,such as Amberlyst-15,Nafion NR50 and Nafion SAC-13.The results showed that the catalytic activity of carbon catalyst was lower than that of Amberlyst-15,but higher than that of Nafion NR50 and Nafion SAC-13.Its cost is much lower than that of Nafion NR50 and Nafion SAC-13.It also showed that carbon-based solid acid catalyst can be prepared by carbonization,activation and sulfonation of pine wood powder. |
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| Keywords: | pine wood powder high specific surface area carbon-based solid acid catalyst |
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