Self-Assembly Syntheses and Crystal Structure of a New Organotin(IV) Schiff Base Complex Containing a Novel Sn5O5 Hydrolysis Ladder |
| |
| Authors: | Chunlin Ma Yawen Han Rufen Zhang |
| |
| Affiliation: | (1) Department of Chemistry, Liaocheng University, Liaocheng, 252059, P.R. China;(2) Department of Chemistry, Taishan University, Taian, 271021, P.R. China |
| |
| Abstract: | A new organotin(IV) Schiff base complex 4 containing a novel Sn5O5 hydrolysis ladder and a disulfide group has been synthesized through a self-assembly reaction. The complex 4 has been characterized by elemental analysis, IR, 1H-, 13C-, and 119Sn-NMR spectra and X-ray crystallography diffraction analyses. The study of the supramolecular structure of complex 4 found that there exist two kinds of C–H···S and C–H···O intermolecular hydrogen bonds. The two kinds of intermolecular hydrogen bonds force the complex 4 into a 2-dimensional “wave” network. The geometry about each tin atom involved is distorted trigonal bipyramid. |
| |
| Keywords: | trizazole organotin(IV) Schiff base crystal structure 2D network |
| 本文献已被 SpringerLink 等数据库收录！ |
|
