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Enhancement of the Photocatalytic Activity Under Visible-Light Irradiation over N-doped TiO2 Modified by Platinum Chloride
Authors:Shinya Higashimoto  Kazuyoshi Takamatsu  Masashi Azuma  Masaaki Kitano  Masaya Matsuoka  Masakazu Anpo
Affiliation:(1) Department of Applied Chemistry, College of Engineering, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan;(2) Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Sakai Osaka, 599-8531, Japan
Abstract:N-doped TiO2 adsorbed platinum chloride (PtCl x /N-TiO2, x being an unidentified number) was found to show much higher photocatalytic activity than either N-TiO2 or PtCl x /TiO2 for the decomposition of acetic acid into CO2 and H2O under Visible-light irradiation, while neither PtCl x /SiO2, PtCl x /Al2O3 nor an aqueous solution of H2PtCl6 was active. An enhancement of the photo-activity on PtCl x /N-TiO2 has been proposed as a Z-scheme mechanism.
Keywords:Visible light  Photocatalyst  N-doped TiO2   Platinum chloride
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