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连续热镀锌表面的钛盐钝化膜研究
引用本文:王宁涛,顾宝珊,杨培燕,宫丽,弋慧丽.连续热镀锌表面的钛盐钝化膜研究[J].电镀与涂饰,2011,30(11):33-37.
作者姓名:王宁涛  顾宝珊  杨培燕  宫丽  弋慧丽
作者单位:中国钢研科技集团有限公司先进金属材料涂镀国家工程实验室,北京,100081
摘    要:研究了一种适用于连续热镀锌钢板表面处理的钛盐钝化膜.通过正交试验和单因素试验,确定了钛盐钝化工艺的最佳条件为:Ti(SO4)2 8 g/L、H2O2 80 mL/L、HNO3 6 mL/L、H3PO46 mL/L,钝化温度30℃,钝化时间1Os.扫描电镜和能谱分析发现,由最佳工艺得到的钝化膜均匀致密,由O、P、Ti和Z...

关 键 词:连续热镀锌  钛盐  钝化膜  耐蚀性  极化电阻

Study on titanium salt passivation coating on surface of continuous hot-dip galvanized sheet
WANG Ning-tao,GU Bao-shan,YANG Pei-yan,GONG Li,YI Hui-li.Study on titanium salt passivation coating on surface of continuous hot-dip galvanized sheet[J].Electroplating & Finishing,2011,30(11):33-37.
Authors:WANG Ning-tao  GU Bao-shan  YANG Pei-yan  GONG Li  YI Hui-li
Affiliation:National Engineering Laboratory for Advanced Coatings Technology of Metal Material,China Iron and Steel Research Institute Group,Beijing 100081,China
Abstract:A titanium salt conversion coating used for continuous hot-dip galvanized steel sheet was studied.The optimal conditions of titanium salt passivation were obtained by orthogonal test and single factor test as follows:Ti(SO4)2 8 g/L,H2O2 80 mL/L,HNO3 6 mL/L,H3PO4 6 mL/L,passivation temperature 30 °C,and passivation time 10 s.The results of SEM and energy-dispersive spectroscopy indicated that the conversion film obtained from the optimal process is uniform and compact,and consists of O,P,Ti,and Zn.Electrochemical test showed that the titanium salt passivation film presents an obvious passivation area,has an increased polarization resistance of 15-17 k?,and can endure more than 24 h in neutral salt spray corrosion test.
Keywords:continuous hot-dip galvanizing  titanium salt  passivation film  corrosion resistance  polarization resistance
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