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介孔TiO2的制备及染料敏化光催化制氢性能研究
引用本文:张伟,沈发治,杜彬. 介孔TiO2的制备及染料敏化光催化制氢性能研究[J]. 广东化工, 2009, 36(10): 108-110
作者姓名:张伟  沈发治  杜彬
作者单位:扬州工业职业技术学院,江苏,扬州,225127;扬州工业职业技术学院,江苏,扬州,225127;扬州工业职业技术学院,江苏,扬州,225127
摘    要:文章利用CTAB为模板剂,以水热法制备介孔TiO2。并用虎红(Rose bengal)进行染料敏化制备了具有可见光活性的光催化剂,分别运甩UV-Vis、XRD、FT-IR和BET等手段对催化剂进行了表征,通过光解水制氢为反应模型考察了所制备催化剂的光催化活性。结果表明:用该方法合成的介孔TiO2具有较高的比表面和催化活性,活性顺序为:介孔TiO2〉P25〉溶胶凝胶捌备的TiO2(500℃煅烧)。

关 键 词:染料敏化  介孔二氧化钛  制氢

Synthesis Mesoporous Dye-sensitized TiO2 and the Performance of Photocatalytic Generating Hydrogen under Visible Light
Zhang Wei,Shen Fazhi,Du Bin. Synthesis Mesoporous Dye-sensitized TiO2 and the Performance of Photocatalytic Generating Hydrogen under Visible Light[J]. Guangdong Chemical Industry, 2009, 36(10): 108-110
Authors:Zhang Wei  Shen Fazhi  Du Bin
Affiliation:(Yangzhou Polytechnic Institute, Yangzhou 225127, China)
Abstract:CTAB was used as template to systhesis mesoporous Titanium Dioxide by the method of hydrothermat. Rose bengal was used as dye-sensitizer to prepare photocatalytic catalyst which had photocatalytic activity under visible light. The samples were characterized by UV-Vis, XRD, FT-IR and BET method respectively. The photocatalytic activities of prepared samples were investigated by photocatalytic decomposition of water into hydrogen. The results indicated that the as-preoared TiO2 had higher surface area and higher photocatalytic activity, activity order:mesoporous TiO2〉P25〉sol-gel TiO2(calcined at 500 ℃).
Keywords:dycsensitization  mesoporousTiO2  hydrogen generation
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