| 苯胺和环氧丙烷共聚物在BMIHSO4中的电化学聚合和表征 |
| |
| 引用本文： | 叶慧,李美超,刘艳娜,马淳安. 苯胺和环氧丙烷共聚物在BMIHSO4中的电化学聚合和表征[J]. 化工学报, 2008, 59(Z1): 98-100 |
| |
| 作者姓名： | 叶慧 李美超 刘艳娜 马淳安 |
| |
| 作者单位： | 浙江工业大学化学工程与材料学院;绿色化学合成技术国家重点实验室培育基地 |
| |
| 基金项目： | 浙江省自然科学基金项目(Y406381); 浙江省分析测试科技计划项目(2008F70029)。~~ |
| |
| 摘 要： | 在1-丁基-3-甲基咪唑硫酸氢盐(BMIHSO4)离子液体中，采用循环伏安法合成了苯胺和环氧丙烷共聚物（PAN-PPO），并与聚苯胺（PAN）进行了对比。结果表明：在相同条件下，PAN-PPO的电合成速度远大于 PAN。同时采用红外光谱FTIR和扫描电子显微镜SEM对PAN-PPO进行了表征，FTIR表明苯胺和环氧丙烷在BMIHSO4中发生了共聚，SEM表明PAN-PPO由直径小于80 nm的纳米纤维组成。
|
| 关 键 词： | 苯胺 环氧丙烷 1-丁基-3-甲基咪唑硫酸氢盐 |
| 收稿时间： | 2008-11-10 |
| 修稿时间： | |
Synthesis and characterization of polyaniline-poly (propylene oxide) prepared in BMIHSO4 ionic liquid |
| |
| YE Hui,LI Meichao,LIU Yanna,MA Chun'an. Synthesis and characterization of polyaniline-poly (propylene oxide) prepared in BMIHSO4 ionic liquid[J]. Journal of Chemical Industry and Engineering(China), 2008, 59(Z1): 98-100 |
| |
| Authors: | YE Hui LI Meichao LIU Yanna MA Chun'an |
| |
| Affiliation: | YE Hui,LI Meichao,LIU Yanna,MA Chun'an (College of Chemical Engineering , Material Science,State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology,Zhejiang University of Technology,Hangzhou 310032,Zhejiang,China) |
| |
| Abstract: | Polyaniline-poly(propylene oxide)(PAN-PPO)was prepared in an ionic liquid 1-butyl-3-methylimidazolium hydrogen sulfate(BMIHSO_4) by cyclic voltammetry.In comparison with polyaniline(PAN),the polymerization rate of PAN-PPO in BMIHSO_4 was much higher than that of PAN.In addition,PAN-PPO was characterized by FTIR spectrometry and scanning electron microscopy(SEM).The result of FTIR showed that aniline and propylene oxide have been copolymerized in the ionic liquid BMIHSO_4,and SEM photograph showed that PAN-P... |
| |
| Keywords: | aniline propylene oxide 1-butyl-3-methylimidazolium hydrogen sulfate |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《化工学报》浏览原始摘要信息 |
|
点击此处可从《化工学报》下载全文 |
