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剪切流场中微孔发泡的气泡成核理论研究现状
引用本文:蔡业彬,国明成,彭玉成,谢存禧.剪切流场中微孔发泡的气泡成核理论研究现状[J].中国塑料,2004,18(2):5-11.
作者姓名:蔡业彬  国明成  彭玉成  谢存禧
作者单位:[1]华南理工大学,广东广州510640 [2]茂名学院机械工程学院,广东茂名525000 [3]北京化工大学,北京100029
基金项目:国家自然科学基金重点基金 (1963 2 0 0 4) (10 172 0 74/A0 2 0 2 0 5 ),广东省科技计划项目 (2 0 0 3C10 3 0 15 )
摘    要:分析了经典成核理论对于动态聚合物熔体中气泡成核的局限性;概括了剪切流场中气泡成核的研究进展,并对剪切流场中泡核拉伸模型、空穴成核模型进行了详细的分析和讨论,指出了其对气泡成核过程解释的不足;介绍了最新的气泡成核中的剪切能成核理论,该理论较完善地解释了剪切流场中气泡成核过程;最后指出了气泡成核研究的发展方向。

关 键 词:剪切流场  气泡成核  自由能  剪切能  成核理论

Research Status Quo of Theory for Cell Nucleation of Microcellular Foam in Shear Flow Field
CAI Ye-bin ,GUO Ming-cheng,PENG Yu-cheng,XIE Cun-xi.Research Status Quo of Theory for Cell Nucleation of Microcellular Foam in Shear Flow Field[J].China Plastics,2004,18(2):5-11.
Authors:CAI Ye-bin    GUO Ming-cheng  PENG Yu-cheng  XIE Cun-xi
Affiliation:CAI Ye-bin 1,2,GUO Ming-cheng3,PENG Yu-cheng1,XIE Cun-xi1
Abstract:Disadvantages of classical theory of cell nucleation in motion polymer melt were analyzed. The research development of cell nucleation in shear flow field was introduced, and the disadvantages of cell stretch model and cavity nucleation model in shear flow field to explain cell nucleation were analyzed and discussed in detail. The lastest shear energy nucleation theory during cell nucleation was recommended, which explained the process of cell nucleation in shear flow field perfectly. Finally, the development trend of cell nucleation was pointed out.
Keywords:shear flow field  cell nucleation  free energy  shear energy  nucleation theory
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