Effects of Forming Conditions and TiC–TiB_2 Contents on the Microstructures of Self-Propagating High-Temperature Synthesized NiAl–TiC–TiB_2 Composites

The NiAl–TiC–TiB2 composites were processed by self-propagating high-temperature synthesis(SHS) method using raw powders of Ni, Al, Ti, B4 C, TiC, and TiB2, and their microstructure and micro-hardness were investigated. The TiC–TiB2 in NiAl matrix, with contents from 10 to 30 wt%, emerged with the use of two methods: in situ formed and externally added. The results show that all final products are composed of three phases of NiAl, TiC, and TiB2. The microstructures of NiAl–TiC–TiB2 composites with in situ-formed TiC and TiB2 are fine, and all the three phases are distributed uniformly. The grains of NiAl matrix in the composites have been greatly refined, and the micro-hardness of NiAl increases from 381 HV100 to 779 HV100. However, the microstructures of NiAl–TiC–TiB2 composites with externally added TiC and TiB2 are coarse and inhomogeneous, with severe agglomeration of TiC and TiB2 particles. The samples containing externally added 30 wt% TiC–TiB2attain the micro-hardness of 485 HV100. The microstructure evolution and fracture mode of the two kinds of NiAl–TiC–TiB2 composites are different.

Effects of Forming Conditions and TiC-TiB2 Contents on the Microstructures of Self-Propagating High-Temperature Synthesized NiAl-TiC-TiB2 Composites

The NiAl-TiC-TiB₂ composites were processed by self-propagating high-temperature synthesis (SHS) method using raw powders of Ni, Al, Ti, B₄C, TiC, and TiB₂, and their microstructure and micro-hardness were investigated. The TiC-TiB₂ in NiAl matrix, with contents from 10 to 30 wt%, emerged with the use of two methods: in situ formed and externally added. The results show that all final products are composed of three phases of NiAl, TiC, and TiB₂. The microstructures of NiAl-TiC-TiB₂ composites with in situ-formed TiC and TiB₂ are fine, and all the three phases are distributed uniformly. The grains of NiAl matrix in the composites have been greatly refined, and the micro-hardness of NiAl increases from 381 HV₁₀₀ to 779 HV₁₀₀. However, the microstructures of NiAl-TiC-TiB₂ composites with externally added TiC and TiB₂ are coarse and inhomogeneous, with severe agglomeration of TiC and TiB₂ particles. The samples containing externally added 30 wt% TiC-TiB₂ attain the micro-hardness of 485 HV₁₀₀. The microstructure evolution and fracture mode of the two kinds of NiAl-TiC-TiB₂ composites are different.