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纳米白炭黑/炭黑并用对SBR硫化胶性能的影响
引用本文:贾红兵,金志刚,文威,王颖,张士齐,王美珣. 纳米白炭黑/炭黑并用对SBR硫化胶性能的影响[J]. 橡胶工业, 2000, 47(9): 515-519
作者姓名:贾红兵  金志刚  文威  王颖  张士齐  王美珣
作者单位:1. 南京理工大学高分子系,江苏南京 210094
2. 马鞍山钢铁公司钢研所,安徽马鞍山 243000
基金项目:国家自然科学基金资助项目(27674013)
摘    要:研究了纳米白炭黑/炭黑并用体系对SBR硫化胶物理性能及磨耗形态的影响,并提出了补强模型。结果表明,纳米白炭黑/炭黑并用体系可提高补强效果,当其并用比为6/24时,硫化胶的拉伸强度和撕裂强度最大,耐磨性最佳。硫化胶补强性能的提高,一方面需要粒子与大分子之间有较强的结合力,另一方面还需要粒子表面上的产生滑移。

关 键 词:白炭黑 炭黑 并用 磨耗 补强 硫化橡胶 丁苯橡胶
文章编号:1000-890(2000)09-0515-05
修稿时间:2000-03-19

Effect of nano-sil ica/carbon black blend on properties of SBR vulcanizate
JIA Hong-bing,JIN Zhi-gang,WEN Wei,WANG Ying,ZHANG Shi-qi and WANG Mei-xun. Effect of nano-sil ica/carbon black blend on properties of SBR vulcanizate[J]. China Rubber Industry, 2000, 47(9): 515-519
Authors:JIA Hong-bing  JIN Zhi-gang  WEN Wei  WANG Ying  ZHANG Shi-qi  WANG Mei-xun
Affiliation:JIA Hong bing 1,JIN Zhi gang 1,WEN Wei 1,WANG Ying 1,ZHANG Shi qi 1,WANG Mei xun 2
Abstract:The effect of nano silica/carbon black blend on the physical properties and abrasion patterns of SBR vulcanizate was investigated and a reinforcement model was proposed.The results showed that the reinforcing effect was improved by using nano silica/carbon black blend;the maximum tensile strength and tear strength,and the optimum abrasion resistance were obtained with 6/24 blending ratio of nano silica/carbon black;not only the higher bonding strength between filler particle and polymer molecule,but also the slippage of polymer molecule on filler particle surface were required for the improved reinforcing effect on the vulcanizate.
Keywords:nano silica  carbon black  blend SBR  abrasion  reinforcement model
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