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Fully Printed Flexible Smart Hybrid Hydrogels
Authors:Yang Zhou  Michael Layani  Shancheng Wang  Peng Hu  Yujie Ke  Shlomo Magdassi  Yi Long
Affiliation:1. School of Materials Science and Engineering, Nanyang Technological University, Singapore;2. Casali Center for Applied Chemistry, Institute of Chemistry, The Center for Nanoscience and Nanotechnology, The Hebrew University of Jerusalem, Jerusalem, Israel
Abstract:A printable hybrid hydrogel is fabricated by embedding poly(N‐isopropylacrylamide) (PNIPAm) microparticles within a water‐rich silica‐alumina(Si/Al)‐based gel matrix. The hybrid gel holds water content of up to 70 wt%, due to its unique Si/Al matrix. The hybrid hydrogel can respond to both heat and electrical stimuli, and can be directly printed layer‐by‐layer using a commercial 3‐dimensional printer, without requiring any curing. The hybrid ink is printed onto a transparent, flexible conductive electrode composed of silver nanoparticles and sustains bending angles of up to 180°, which enables patterning of various flexible devices such as smart windows and a 3D optical waveguide valve.
Keywords:3D printing  hydrogels  PNIPAm  smart windows  thermochromics
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