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Dopamine: Just the Right Medicine for Membranes
Authors:Hao‐Cheng Yang  Ruben Z Waldman  Ming‐Bang Wu  Jingwei Hou  Lin Chen  Seth B Darling  Zhi‐Kang Xu
Affiliation:1. Nanoscience and Technology Division, Argonne National Laboratory, Lemont, IL, 60439, USA;2. Institute for Molecular Engineering, University of Chicago, Chicago, IL, USA;3. MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, China;4. UNESCO Centre for Membrane Science and Technology, School of Chemical Engineering, University of New South Wales, Sydney, Australia;5. Department of Materials Science and Metallurgy, University of Cambridge, Cambridge, UK;6. Energy Systems Division, Argonne National Laboratory, Lemont, IL, USA;7. Institute for Molecular Engineering, Argonne National Laboratory, Lemont, IL, USA
Abstract:Mussel‐inspired chemistry has attracted widespread interest in membrane science and technology. Demonstrating the rapid growth of this field over the past several years, substantial progress has been achieved in both mussel‐inspired chemistry and membrane surface engineering based on mussel‐inspired coatings. At this stage, it is valuable to summarize the most recent and distinctive developments, as well as to frame the challenges and opportunities remaining in this field. In this review, recent advances in rapid and controllable deposition of mussel‐inspired coatings, dopamine‐assisted codeposition technology, and photoinitiated grafting directly on mussel‐inspired coatings are presented. Some of these technologies have not yet been employed directly in membrane science. Beyond discussing advances in conventional membrane processes, emerging applications of mussel‐inspired coatings in membranes are discussed, including as a skin layer in nanofiltration, interlayer in metal‐organic framework based membranes, hydrophilic layer in Janus membranes, and protective layer in catalytic membranes. Finally, some critical unsolved challenges are raised in this field and some potential pathways are proposed to address them.
Keywords:Janus membranes  membranes  metal‐organic framework membranes  nanofiltration  photocatalysis  polydopamine
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