2D or Not 2D: Strain Tuning in Weakly Coupled Heterostructures |
| |
Authors: | Ruining Wang Felix R L Lange Stefano Cecchi Michael Hanke Matthias Wuttig Raffaella Calarco |
| |
Affiliation: | 1. Paul‐Drude‐Institut für Festk?rperelektronik, Berlin, Germany;2. I. Physikalisches Institut (IA), RWTH Aachen University, Aachen, Germany;3. JARA‐Institut Green IT, JARA‐FIT Forschungszentrum Jülich GmbH and RWTH Aachen University, Aachen, Germany |
| |
Abstract: | A route to realize strain engineering in weakly bonded heterostructures is presented. Such heterostructures, consisting of layered materials with a pronounced bond hierarchy of strong and weak bonds within and across their building blocks respectively, are anticipated to grow decoupled from each other. Hence, they are expected to be unsuitable for strain engineering as utilized for conventional materials which are strongly bonded isotropically. Here, it is shown for the first time that superlattices of layered chalcogenides (Sb2Te3/GeTe) behave neither as fully decoupled two‐dimensional (2D) materials nor as covalently bonded three‐dimensional (3D) materials. Instead, they form a novel class of 3D solids with an unparalleled atomic arrangement, featuring a distribution of lattice constants, which is tunable. A map to identify further material combinations with similar characteristic is given. It opens the way for the design of a novel class of artificial solids with unexplored properties. |
| |
Keywords: | molecular beam epitaxy phase change materials strain engineering superlattices van der Waals epitaxy |
|
|