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氯苯肟唑(SPRI-WM-005)异构体的分离及其杀菌活性
引用本文:陈亮,袁莉萍,曹瑾,倪长春,沈宙,栗秀丽,张一宾.氯苯肟唑(SPRI-WM-005)异构体的分离及其杀菌活性[J].农药,2007,46(7):447-448,466.
作者姓名:陈亮  袁莉萍  曹瑾  倪长春  沈宙  栗秀丽  张一宾
作者单位:上海市农药研究所,上海,200032;上海市农药研究所,上海,200032;上海市农药研究所,上海,200032;上海市农药研究所,上海,200032;上海市农药研究所,上海,200032;上海市农药研究所,上海,200032;上海市农药研究所,上海,200032
基金项目:国家科技支撑计划;上海市科委资助项目
摘    要:氯苯肟唑(SPRI-WM-005)是含顺、反异构体的肟醚结构化合物。为了研究两个异构体及未分离的混合物在生物活性上是否存在差异,对两个异构体进行了分离,并做了对黄瓜白粉病的室内生物活性测定。结果表明,当处理剂量为50mg/L时,氯苯肟唑(Z,E混合物)、Z-氯苯肟唑和E-氯苯肟唑的防效分别为95%、100%和97%,三者活性基本相当,故在实际中无须将两个异构体分离,混合体可直接应用。

关 键 词:氯苯肟唑  异构体  分离  杀菌活性
文章编号:1006-0413(2007)07-0447-02
修稿时间:2007-01-25

Separation of the Isomers and the Fungicidal Activity for SPRI-WM-005
CHEN Liang,YUAN Li-ping,CAO Jin,NI Chang-chun,SHEN Zhou,LI Xiu-li,ZHANG Yi-bin.Separation of the Isomers and the Fungicidal Activity for SPRI-WM-005[J].Pesticides,2007,46(7):447-448,466.
Authors:CHEN Liang  YUAN Li-ping  CAO Jin  NI Chang-chun  SHEN Zhou  LI Xiu-li  ZHANG Yi-bin
Affiliation:Shanghai Pesticide Research Institute, Shanghai 200032, China
Abstract:SPRI-WM-005 is a new oxime ether compound, which has E and Z isomers. In order to study the activity of Z, E isomers and the mixture of the isomers, the isomers were separated. The bioassays showed that the inhabitation rate of the mixture of two isomers, Z isomer and E isomer were reached 95 %, 100% and 97% against Sphaerotheca fuliginea at 50 mg/L. The inhabitation rate of them was similar, so the mixture of the two isomers can be used without separation.
Keywords:SPRI-WM-005  isomer  separation  fungicidal activity
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