| 氯丙烯催化环氧化钛催化剂研究进展 |
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| 引用本文： | 王庆法,王莅. 氯丙烯催化环氧化钛催化剂研究进展[J]. 化学工业与工程, 2004, 21(5): 351-355 |
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| 作者姓名： | 王庆法 王莅 |
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| 作者单位： | 绿色合成与转化教育部重点实验室,天津大学化工学院,天津,300072 |
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| 基金项目： | 国家重点基础研究发展规划项目(G2000048005) |
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| 摘 要： | 主要介绍了TiO2／SiO2、TS-1及其改性的TS-1等催化剂催化氯丙烯直接环氧化制备环氧氯丙烷的近期研究进展，对各方法的特点和发展前景进行了讨论，并指出了氯丙烯直接环氧化制备环氧氯丙烷的难点和发展趋势。
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| 关 键 词： | 环氧氯丙烷 钛催化剂 氯丙烯 催化环氧化 |
| 文章编号： | 1004-9533(2004)05-0351-05 |
| 修稿时间： | 2003-11-16 |
Progress in Titanium Catalysts Used for Epoxidation of Allyl Chloride |
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| WANG Qing-fa,WANG Li School of Chemical Engineering,Tianjin University,Tianjin ,China). Progress in Titanium Catalysts Used for Epoxidation of Allyl Chloride[J]. Chemical Industry and Engineering, 2004, 21(5): 351-355 |
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| Authors: | WANG Qing-fa WANG Li School of Chemical Engineering Tianjin University Tianjin China) |
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| Affiliation: | WANG Qing-fa,WANG Li School of Chemical Engineering,Tianjin University,Tianjin 300072,China) |
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| Abstract: | Epichlorohydrin is an important chemical intermediate with wide and prosperous application.In this paper,the recent progress in the synthesis of epichlorohydrin by direct epoxidation of allyl chloride catalyzed by TiO_2/SiO_2,TS-1 and the modified TS-1 catalysts is introduced.The features and prospect of the different processes are discussed.The difficulties in the research of direct allyl chloride oxidation and the developing trend are pointed out. |
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| Keywords: | epichlorohydrin titanium catalysts allyl chloride catalytic epoxidation |
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