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Enhancement of the Thermoelectric Performance of Bi0.4Sb1.6Te3 Alloys by In and Ga Doping
Authors:Kyu-Hyoung Lee  Sungwoo Hwang  Byungki Ryu  Kyunghan Ahn  Jongwook Roh  Daejin Yang  Sang-Mock Lee  Hyunsik Kim  Sang-Il Kim
Affiliation:1. Advanced Materials Research Center, Samsung Advanced Institute of Technology, Yong-In, 446-712, South Korea
2. Department of Materials Science, California Institute of Technology, Pasadena, CA, 91125, USA
Abstract:We report an enhancement of the thermoelectric figure of merit in polycrystalline In- and Ga-doped Bi0.4Sb1.6Te3 compounds. Via the controlled doping of In or Ga, the lattice thermal conductivity was effectively reduced by strong point-defect phonon scattering while the power factor was not significantly changed due to the similarity of the density of states near the valence-band maximum between undoped and In- or Ga-doped compositions. An enhanced ZT of 1.2 at 320 K was obtained in 0.5 at.% In-doped Bi0.4Sb1.6Te3 compound by these synergetic effects.
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