Synthesis and nonlinear optical properties of soluble fluorinated polyimides containing hetarylazo chromophores with large hyperpolarizability |
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Authors: | Man He Jia Dai Yiping Cui |
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Affiliation: | a School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China b Department of Electronic Engineering, Southeast University, Nanjing 210096, China |
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Abstract: | The novel fluorinated polyimides with side-chain nonlinear optical (NLO) chromophores were synthesized from hydroxyl polyimides, followed by the Mitsunobu reaction with NLO chromophores. Molecular structural characterization for the resulting polymers was achieved by 1H NMR, FT-IR, UV-Vis spectra, elemental analysis and gel permeation chromatography (GPC). The polymers exhibit excellent solubility in common organic solvents, good film-forming properties, high glass transition temperature (Tg) in the range from 193 to 200 °C and thermal stability up to 290 °C. The polyimides P1 and P2 containing hetarylazo chromophores with large hyperpolarizability possess a high electro-optic (EO) coefficient (r33), which is larger than that of the polyimide P3 attached DR1. Excellent temporal stability and low optical losses in the range of 1.9-2.1 dB/cm at 1.55 μm were observed for these polymers. Such new NLO fluorinated polyimides are distinguished by an excellent combination of NLO activity, temporal stability, and optical loss. |
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Keywords: | Polyimides Hetarylazo chromophores Nonlinear optics |
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