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高效气-液双相CO2缓蚀剂的研究
引用本文:张军平,张秋禹,颜红侠,赵雯,张玉芳,路民旭.高效气-液双相CO2缓蚀剂的研究[J].腐蚀科学与防护技术,2003,15(4):241-243.
作者姓名:张军平  张秋禹  颜红侠  赵雯  张玉芳  路民旭
作者单位:1. 西北工业大学化学工程系,西安,710072
2. 中国石油天然气总公司管材研究所,西安,710065
摘    要:以吗啉、三聚甲醛、二正丁胺为原料合成了一种吗啉 衍生物,以异丁醛、氨水和硫为原料合成了一种噻唑衍生物.采用静态挂片失重法,研究了两种衍生物及其与其它缓蚀剂复配后对CO2腐蚀的缓蚀效果.结果表明,该吗啉衍生物与咪唑啉衍生物、硫脲及丙炔醇复配后对CO2腐蚀有很好的缓蚀效果;而噻唑衍生物单独使用时对CO2腐蚀有较好的缓蚀效果,其它常用缓蚀剂中只有丙炔醇对其有协同促进作用.这两种复配缓蚀剂都是高效气-液双相缓蚀剂.

关 键 词:缓蚀剂  二氧化碳  吗啉
文章编号:1002-6495(2003)03-0241-03
修稿时间:2001年12月27

HIGH EFFICIENT INHIBITORS FOR STEEL IN VAPOR-LIQUID PHASES
ZHANG Jun ping ,ZHANG Qiu yu ,YAN Hong xia ,ZHAO Wen ,ZHANG Yu fang ,LU Min xu.HIGH EFFICIENT INHIBITORS FOR STEEL IN VAPOR-LIQUID PHASES[J].Corrosion Science and Protection Technology,2003,15(4):241-243.
Authors:ZHANG Jun ping  ZHANG Qiu yu  YAN Hong xia  ZHAO Wen  ZHANG Yu fang  LU Min xu
Affiliation:ZHANG Jun ping 1,ZHANG Qiu yu 1,YAN Hong xia 1,ZHAO Wen 1,ZHANG Yu fang 2,LU Min xu 2 1 Department of Chemical Engineering,Northwestern Polytechnical University,Xi'an 710072,China, 2 Tubular Goods Research Center of China National Petroleum Corporation,Xi'an 710065,China
Abstract:A kind of morpholine derivative was synthesized by morpholine,trioxane and dibutylamines,and a thiazole derivative was synthesized by morpholine,ammonia and sulfur.The corrosion inhibition efficiency of the two derivatives and their mixtures with other corrosion inhibitors were studied by static weightloss measurement.Results show that the mixture of morpholine derivative with imidazoline derivative,thiocarbamide and propiolic alcohol has a good inhibitive efficiency for CO 2 induced corrosion.But thiazole derivative has a good inhibitive efficiency for CO 2 induced corrosion when used individually,and among the common used inhibitors only propiolic has synergism effect with thiazole derivative.The two corrosion inhibitors are both high efficient inhibitors for CO 2 induced corrosion in vapor-liquid phases.
Keywords:corrosion inhibitor  carbon dioxide  morpholine  thiazole  thiocarbamide  propiolic alcohol
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