Cooperative Quantum Cutting in Yb $^{3+}$–Tb $^{3+}$ Codoped Borosilicate Glasses

Quantum cutting down-conversion (DC) with the emission of two near-infrared photons for each blue photon absorbed is realized in $hbox{Yb}^{3+}hbox{–}hbox{Tb}^{3+}$ codoped borosilicate glasses. With the excitation of $hbox{Tb}^{3+}$ ion by a 484-nm monochromatic light, emission from the $^{2} hbox{F} _{5/2}rightarrow ^{2} hbox{F} _{7/2}$ transition of $hbox{Yb}^{3+}$ ions is observed and this emission is proved to originate from the DC between $hbox{Tb}^{3+}$ ions and $hbox{Yb}^{3+}$ ions. Results shows that maximum quantum efficiency reach as high as 153%, which is comparable with that in oxyfluoride glass ceramics in this system. With the advantages of excellent transparence, easy shaping, good stability, and low cost, $hbox{Yb}^{3+}hbox{–}hbox{Tb}^{3+}$ codoped borosilicate glasses are potentially used as down-converter layer in silicon-based solar cells.