Film Blowing of Layered Silicate Nanocomposites |
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Authors: | Taner E Dirama Lloyd A Goettler |
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Affiliation: |
a Department of Polymer Science, The University of Akron, Akron, Ohio, USA
b Department of Polymer Engineering, The University of Akron, Akron, Ohio, USA |
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Abstract: | Bubble formation and stability in the film blowing processing of in situ polymerized and melt-compounded polyamide 6-based layered silicate nanocomposites (LSNs) are correlated to their underlying rheology, structure, and crystallization behavior. The layered silicates enhance melt elasticity, induce γ -form crystallinity, and increase crystallization rates without having any significant effect on the extent of crystallinity. A bubble stability quantification method employed to assess the level of instability during the film blowing process finds the in situ polymerized LSNs to be more stable than PA6, while melt-compounded LSNs do not display such an improved processability. All of the LSN films produced by film blowing possess superior mechanical properties compared to neat nylon 6, despite their relatively rougher film surfaces. |
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Keywords: | Blowing Crystallization Film Montmorillonite Nanocomposite Nylon Rheology Silicate Stability |
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