| 新型桥联铁硫簇合物的合成与表征 |
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| 引用本文： | 韩聪,郭艳玲,黄骁南,刘伟.新型桥联铁硫簇合物的合成与表征[J].广州化工,2010,38(6):79-80,87. |
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| 作者姓名： | 韩聪 郭艳玲 黄骁南 刘伟 |
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| 作者单位： | 天津科技大学理学院,天津,300457 |
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| 基金项目： | 天津科技大学科学研究基金资助项日 |
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| 摘 要： | 通过2-呋喃甲硫醇/十二羰基三铁/三乙胺体系所形成的中间物(μ-2-C4H3OCH2S)(μ-CO)Fe2(CO)6]Et3NH在室温下同亲电试剂C lSZSC l原位反应,合成了三个新颖桥联双核铁硫簇合物(μ-2-C4H3OCH2S)Fe2(CO)6]2(μ-S-Z-S-μ)(Z=CH2CH2CH2CH2,CH2(CH2OCH2)2CH2,CH2(CH2OCH2)3CH2)。这三个新颖配合物均通过1H NMR,IR和元素分析表征。
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| 关 键 词： | 铁硫簇合物 μ-CO负离子 2-呋喃甲硫醇 |
Synthesis and Structures of New Bridged Butterfly-shaped Fe-S Cluster Complexes |
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| HAN Cong,GUO Yan-ling,HUANG Xiao-nan,LIU Wei.Synthesis and Structures of New Bridged Butterfly-shaped Fe-S Cluster Complexes[J].GuangZhou Chemical Industry and Technology,2010,38(6):79-80,87. |
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| Authors: | HAN Cong GUO Yan-ling HUANG Xiao-nan LIU Wei |
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| Affiliation: | (College of Science,Tianjn University of Science and Technology,Tianjin 300457,China) |
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| Abstract: | Through the situ reaction of electrophilic reagents ClSZSCl with the complex salts （μ-2-C4H3OCH2S）（μ-CO）Fe2（CO）6]Et3NH derived from the system of Fe3（CO）12,2-furyl methanethiol and triethylamine,three new bridged double butterfly-shaped clusters （μ-2-C4H3OCH2S）Fe2（CO）6]2（μ-S-Z-S-μ）（Z= CH2CH2CH2CH2,CH2（CH2OCH2）2CH2,CH2（CH2OCH2）3CH2） were obtained.The structures of the three new compounds were fully characterized by elemental analysis,IR and 1H NMR spectroscopies. |
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| Keywords: | butterfly-shaped sulfur-iron clusters μ-CO anions salts 2-furylmethanethiol |
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