Activity and stability of Pd/MMnOx (M = Co,Ni, Fe and Cu) supported on cordierite as CO oxidation catalysts |
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| Authors: | Qiong Huang Xiaokang Yan Bing Li Xiaoliang Xu Yingwen Chen Shemin Zhu Shubao Shen |
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| Affiliation: | 1. State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China;2. College of Materials Science and Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China |
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| Abstract: | Several catalysts of the general formula, MMnOx (M = Co, Ni, Fe and Cu), were synthesised through the impregnation method; their activities were shown to be enhanced by the addition of a small amount of Pd (0.01–0.1 wt%). These catalysts exhibit different activities for the catalytic oxidation of CO, due to the different valence states of various transition metal oxides. The introduction of Pd prominently enhanced both the reduction and oxidation capabilities of the catalysts. These catalysts were optimised for oxidation activities by designing orthogonal experiments. Based upon the catalysts’ properties, the stability of these samples and their ability to resist steam over Pd/CoMnOx/cordierite were investigated. |
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