| 环境友好型丙烯酸酯压敏胶的研究 |
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| 引用本文： | 陈榕珍,李国庆,成荣明.环境友好型丙烯酸酯压敏胶的研究[J].高分子材料科学与工程,2005,21(6):247-250. |
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| 作者姓名： | 陈榕珍 李国庆 成荣明 |
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| 作者单位： | 1. 华东师范大学,纳米功能材料和器件应用研究中心,上海,200062
2. 三信化学(上海)有限公司,上海,200063 |
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| 摘 要： | 采用本体聚合方法,以Co螯合物自由基为引发剂,合成温度可控,制备出一种新型环境友好的丙烯酸酯压敏胶.CoN、ABL和O2的共引发体系对丙烯酸酯单体产生可持续的引发效果.在相同的分子量条件下,其粘着性能与溶剂型压敏胶的效果相当.
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| 关 键 词： | 丙烯酸酯压敏胶 本体聚合 持续引发效果 环保 |
| 文章编号： | 1000-7555（2005）06-0247-04 |
| 收稿时间： | 2004-08-12 |
| 修稿时间： | 2004-11-19 |
STUDY ON THE ENVIRONMENTAL FRIENDLY ACRYLATE PRESSURE SENSITIVE ADHESIVE |
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| CHEN Rong-zhen,LI Guo-qing,CHENG Rong-ming.STUDY ON THE ENVIRONMENTAL FRIENDLY ACRYLATE PRESSURE SENSITIVE ADHESIVE[J].Polymer Materials Science & Engineering,2005,21(6):247-250. |
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| Authors: | CHEN Rong-zhen LI Guo-qing CHENG Rong-ming |
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| Affiliation: | 1. Nanotech Center, East China Normal University, Shanghai 200062, China; 2. 3X Chemistry (Shanghai |
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| Abstract: | A new environmental friendly acrylate pressure sensitive adhesive was prepared by using cobalt-mediated free radical to control the bulk polymerization of acrylate monomers.The perfect effect of controllable temperature synthetical technology was achieved.There is the persistent radical effect on acrylate monomers using CoN,ABL and O_2 as co-catalyst.The synthesis discipline of the acrylic copolymer and the influences of N_2,CoN, ABL,NDM and AA content on copolymer component were discussed in the paper.The adhesive property of this acrylate pressure sensitive adhesive was equal to that of the solvent acrylate pressure sensitive adhesive with the close molecular weight and polydispersity index. |
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| Keywords: | acrylate pressure sensitive adhesive bulk polymerization persistent radical effect environmental protection |
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