Role of structural modification on the electrical properties of poly(ethylene terephthalate) irradiated with 90‐MeV carbon ion beam |
| |
| Authors: | A Srivastava V Singh P Kulriya S Vyas P Sen SK Bandopadhay TV Singh |
| |
| Affiliation: | 1. Department of Chemistry and Centre of Advanced Studies in Chemistry, Panjab University, Chandigarh 160014, India;2. Materials Science Group, Inter University Accelerator Centre, New Delhi 110067, India;3. Physics Group, Variable Energy Cyclotron Centre, Bidhannagar, Kolkata 700064, India |
| |
| Abstract: | Thin films of poly(ethylene terephthalate) (PET) having a thickness of 100 μm were exposed to different ion fluence of swift heavy ions of carbon in the range of 5 × 1011 – 5 × 1013 ions/cm2. The effect of ion beam on structural and electrical modification has been studied by UV/vis, FTIR, X‐ray diffraction (XRD), Differential Scanning Calorimetery (DSC), and AC electrical measurement techniques. On irradiation, a shift in absorption wavelength toward the red end of spectrum with increase of ion fluence was observed. The intensity of crystalline IR bands and main diffraction peak in XRD pattern were found to decrease with increase in ion fluence. It indicates the loss of crystallinity induced by ion‐beam irradiation. The crystallite size was found to increase on irradiation. The melting temperature (Tm) of PET films increased at a low ion dose (5.0 × 1012 ions/cm2), while it decreased at higher ion fluence (50.0 × 1012 ions/cm2). The dielectric constant (ε′) of PET films was increased with increase of ion fluence. The modifications brought about in the dielectric constant are correlated with chemical and molecular structural changes occurring on irradiation. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers. |
| |
| Keywords: | |
|
|
