Metal clusters and nanoparticles assembled in zeolites: an example of stable materials with controllable particle size |
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Affiliation: | 1. Physico-Chemical Research Institute, Belarusian State University, Leningradskaja Str., 14, Minsk, 220080, Belarus;2. CCMC-UNAM, Ensenada, B.C., 22800, Mexico |
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Abstract: | An ion-exchangeable zeolite (mordenite) is used to control the formation of nanoparticles and clusters within the solid matrix by the hydrogen reduction of metal ions (Ag+, Cu2+, and Ni2+). SiO2/Al2O3 molar ratio in mordenite appears to be an efficient tool to manage the reducibility of the metal ions. Few-atomic silver clusters in line with the larger silver nanoparticles were observed with DRS for the reduced Ag+-exchanged mordenites. Cu2+-exchanged ones produce the copper nanoparticles with different optical appearance, and Ni2+-exchanged mordenites are reduced up to complicated species with no explicit assignment of metal particles under the conditions studied. |
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