Hydrierung von p‐Nitrophenol zu p‐Aminophenol als Testreaktion für die katalytische Aktivität von Pt‐Trägerkatalysatoren

The hydrogenation of p‐nitrophenol (PNP) to p‐aminophenol (PAP) using NaBH₄ as a reducing agent was studied as a test reaction for determining the catalytic activity of supported Pt catalysts. The initial reaction rate, which is accessible within less than 10 minutes via online UV‐vis spectroscopy at room temperature, ambient pressure and in water as a solvent, was used as measure for the catalytic activity. For three Pt catalysts supported on porous SiO₂, porous glass and Al₂O₃, respectively, significant differences in the catalytic activity were observed. However, especially in case of very active catalysts, limitations of the reaction by internal or external mass transfer have to be considered.