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Transport Properties of Polycrystalline La_(2/3)Ca_(1/3)Mn_(1-x)Cu_xO_3 Prepared by Sol-Gel
作者姓名:杨应平
作者单位:YANG Ying-ping 1,2) YUAN Song-liu 1) XIA Zheng-cai 1) ZHANG Guo-hong 1) ZHANG Li-jiang 1) 1)Huazhong University of Science and Technology 2)Wuhan University of Technology
基金项目:NationalNaturalScienceFoundationofChina (GrantNo .10 1740 2 2 )
摘    要:1 IntroductionManganeseperovskites ,suchasR1-yAyMnO3 (R =rare earthelement,A =divalentelement) ,areattractingconsiderabletheoreticandtechnologicalinterestsbyvirtueofthediscoveryofthecolossalmagnetoresistance(CMR) 1,2 ] .CMRiscausedbythecomplexnatureofin terplayof…


Transport Properties of Polycrystalline La2/3Ca1/3Mn1-x CuxO3 Prepared by Sol-Gel
YANG Ying-ping,YUAN Song-liu,XIA Zheng-Cai,ZHANG Guo-hong,ZHANG Li-Jiang.Transport Properties of Polycrystalline La_(2/3)Ca_(1/3)Mn_(1-x)Cu_xO_3 Prepared by Sol-Gel[J].Journal of Wuhan University of Technology. Materials Science Edition,2002,17(4).
Authors:YANG Ying-ping  YUAN Song-liu  XIA Zheng-Cai  ZHANG Guo-hong  ZHANG Li-Jiang
Abstract:The influence of Cu dopant (x) and sintering temperature (T s) on the transport properties of La 2/3Ca 1/3Mn 1-xCu xO 3 series samples prepared by Sol-Gel technique was investigated.X-ray diffraction patterns show that all the samples with different Cu dopant and sintering temperatures (T s) are of single phase without obvious lattice distortion.Experimental results indicate that the insulator-metal transition temperature is directly related to the sintering temperature and Cu dopant x.It is interesting to observe that a proper amount of Cu dopant can substantially improve magnetoresistance effects.
Keywords:Cu doping  sol-gel  intergrain magnetoresistance
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