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Electrocatalytic effects of Mo–Pt intermetallics singly and with ionic activators. Hydrogen production via electrolysis
Authors:Dragica Lj. Stojić  Tomislav D. Grozdić  Milica P. Marčeta Kaninski  Vojislav Đ. Stanić
Affiliation:1. Laboratory of Physical Chemistry, Vin?a Institute of Nuclear Sciences, P.O. Box 522, 11001-Belgrade, Serbia and Montenegro;2. Centre for Multidisciplinary Studies, University of Belgrade, 11030-Belgrade, Serbia and Montenegro
Abstract:The intermetallic phases along the Pt–Mo phase diagram, singly or in combination with specific ionic activators, have been investigated as cathode materials for the production of hydrogen by electrolysis from water KOH solutions in an attempt to decrease energy consumption. The influence of ionic activators (activating compounds) on energy consumption was significant. The intermetallic phases, as cathode materials, were activated by the surface deposition of activating compounds from electrolyte. The influence of these cathode materials on the electrolytic evolution of hydrogen was discussed in the context of transition metals features and their electronic configuration.
Keywords:Hydrogen production   Electrocatalysis   Ionic activators   Intermetallics   Energy consumption
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