| P(MMA-DBMEA)乳液聚合研究 |
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| 引用本文： | 张金枝,柴仕淦,王世敏,宋功武,程时远. P(MMA-DBMEA)乳液聚合研究[J]. 胶体与聚合物, 2004, 22(3): 35-37 |
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| 作者姓名： | 张金枝 柴仕淦 王世敏 宋功武 程时远 |
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| 作者单位： | 湖北大学化学与材料科学学院,武汉,430062 |
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| 摘 要： | 甲基丙烯酸甲酯 ( MMA)在无皂乳化剂条件下 ,加入少量的功能性单体 N,N一二甲基 ,N-丁基 ,N-甲基丙烯酰氧乙基溴化铵 ( DBMEA) ,合成了稳定的 P( MMA-DBMEA)共聚物乳液 .该共聚物乳胶粒呈现单分散分布。同时用 NMR研究了共聚物 ,并对 P( MMA-DBMEA)聚合物13 C进行了全归属。
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| 关 键 词： | 无皂阳离子P(MMA-DBMEA)乳液 CP/MAS SW NMR 结构解析 |
| 修稿时间： | 2004-04-16 |
The study on the Emulision Polymerization of P(MMA-DBMEA) |
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| Zhang Jinzhi Chai Shigan Wang Shimin Song Gongwu Cheng Shiyuan. The study on the Emulision Polymerization of P(MMA-DBMEA)[J]. Chinese Journal of Colloid and Polymer, 2004, 22(3): 35-37 |
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| Authors: | Zhang Jinzhi Chai Shigan Wang Shimin Song Gongwu Cheng Shiyuan |
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| Affiliation: | Faculty of Chemistry and Material Science Hubei University Wuhan 430062 |
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| Abstract: | Preparation of cationic copolymer latex of MMA with comonomer N, N-dimethyl, N-butyl, N-methacryloloxylethyl ammonium bromide (DBMEA) was carried out by soap-free emulsion polymerization. The 13 C NMR spectroscopy of P(MMA-DBMEA) polymes was studied by SW probe and CP/MAS probe. and 13C chemical shifts of the polymer were assigned. |
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| Keywords: | Emulsifier-free P(MMA-DBMEA) cationic emulsion CP/MAS SW 13 C NMR Polymer structure analyzed |
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