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苏氨酸水溶液在298.15K到328.15K区间液相扩散系数的测定和关联
引用本文:赵长伟,马沛生. 苏氨酸水溶液在298.15K到328.15K区间液相扩散系数的测定和关联[J]. 中国化学工程学报, 2004, 12(2): 267-271
作者姓名:赵长伟  马沛生
作者单位:SchoolofChemicalEngineeringandTechnology,Tianjinuniversity,Tianjin300072,China
基金项目:Supported by the Educational Ministry Doctor Foundation of China (No. 2000005608).
摘    要:The diffusion coefficients of aqueous L-threonine solutions were determined from 298.15K to 328.15K by the metallic diaphragm cell method with accuracy, promptness and convenience. Meanwhile, the densities and viscosities of the solutions were also determined and correlated. Based on a seml-empirical model for correlating the diffusion coefficients of some amino acids in their aqueous solutions, a new semi-empirical model for correlating the diffusion coefficients involving temperature was provided, which is more comprehensive and less experiment dependent compared to the previous model. The fitting results are satisfactory. Compared to a former model for correlating the diffusion coefficients of solid organic salts in their aqueous solutions, this model provides significant improvement in correlation of diffusion coefficients with different temperatures avoiding arduous work.

关 键 词:流体扩散系统 水合L-苏氨酸溶液 液体 横隔膜 温度
修稿时间: 

Measurement and Correlation on Liquid Diffusion Coefficients of Aqueous L-Threonine Solutions from 298.15K to 328.15K
ZHAO Changwei,MA Peisheng. Measurement and Correlation on Liquid Diffusion Coefficients of Aqueous L-Threonine Solutions from 298.15K to 328.15K[J]. Chinese Journal of Chemical Engineering, 2004, 12(2): 267-271
Authors:ZHAO Changwei  MA Peisheng
Affiliation:School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
Abstract:The diffusion coefficients of aqueous L-threonine solutions were determined from 298.15 K to 328.15 K by the metallic diaphragm cell method with accuracy, promptness and convenience. Meanwhile, the densities and viscosities of the solutions were also determined and correlated. Based on a semi-empirical model for correlating the diffusion coefficients of some amino acids in their aqueous solutions, a new semi-empirical model for correlating the diffusion coefficients involving temperature was provided, which is more comprehensive and less experiment dependent compared to the previous model. The fitting results are satisfactory. Compared to a former model for correlating the diffusion coefficients of solid organic salts in their aqueous solutions, this model provides significant improvement in correlation of diffusion coefficients with different temperatures avoiding arduous work.
Keywords:L-threonine  diffusion coefficient  metallic diaphragm cell method  semi-empirical model
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