我国铜、铅阳极泥脱砷工艺研究现状

在铜、铅阳极泥综合回收多种稀贵金属过程中,高毒性砷元素在各个生产环节均有分散,严重影响稀贵金属回收率及产品质量.砷元素随着冶炼工艺流程最终进入焙烧烟气、生产废水和废渣中,若处置不当将成为污染环境的重大安全隐患,铜、铅阳极泥的高效脱砷对砷污染防控具有重要意义.现有阳极泥脱砷工艺主要包括火法、湿法和火法-湿法联合,文章对上...

Research status of arsenic removal technology from copper and lead anode slime

In the process of comprehensive recovery of various rare and precious metals from copper and lead anode slime,highly toxic arsenic elements are dispersed in all production links,which seriously affect the recovery rate and product quality of rare and precious metals.The arsenic element finally enters the roasting flue gas,production waste water and waste residue along with the smelting process.If improperly disposed of,it will become a major safety hazard that pollutes the environment.Therefore,the efficient arsenic removal from copper and lead anode slime is of great significance to the prevention and control of arsenic pollution.The existing arsenic removal processes of anode slime mainly include pyrometallurgy,hydrometallurgy and combination of the first two.In this paper,the aforementioned processes were introduced in detail.The pros and cons of each process were analyzed and compared.Based on the problems of serious environmental pollution,low selectivity for target element and intractable treatment of three wastes in the existing process,it is the research direction of comprehensive treatment of copper and lead anode slime to develop arsenic removal technology with low cost,short process,high efficiency and environmental friendliness.