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Synthesis and Characterization of Lanthanide Complexes Involving Cyclopentadienyl and Benzohydroximic Acid Ligand
Authors:WANG Xiu-ran  WAN Yu-bao  HU Ji-ping
Abstract:The glasses of 59 5H 3BO 3 40XF n 0 5Eu 2O 3 (X=Ca, Mg, Y, Pb, n =2 or 3) were prepared. The measurement of phonon sideband was performed. The higher energy range of phonon sideband spectra was fitted by Gaussian function, and the electron phonon coupling constant was calculated. The decreasing order of electron phonon coupling constant is from CaF 2, YF 3, MgF 2 to PbF 2, and the phonon sideband spectra are coincide with Raman scattering spectra.
Keywords:rare earths  benzohydroximic acid  lanthanide complexes  synthesis
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