| 载体表面化学状态对Pt/C催化剂结构及电催化活性的影响 |
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| 引用本文： | 段建军,刘硕,张正富,孙力军,杨喜昆,徐洋洋,徐明丽.载体表面化学状态对Pt/C催化剂结构及电催化活性的影响[J].功能材料,2011,42(1):83-87. |
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| 作者姓名： | 段建军 刘硕 张正富 孙力军 杨喜昆 徐洋洋 徐明丽 |
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| 作者单位： | 昆明理工大学分析测试研究中心; |
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| 基金项目： | 国家自然科学基金资助项目(20863003); 云南省应用基础研究面上资助项目(2008ZC031M); 云南省中青年学术技术带头人后备人才培养资助项目(2007PY01-9) |
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| 摘 要： | 对碳黑进行不同条件的氧化处理得到不同表面化学状态的载体,以甲醛为还原剂,氯铂酸为前驱体,制备Pt/C电催化剂.运用X射线光电子能谱(XPS)、X射线衍射(XRD)、透射电镜(TEM)等分析手段研究碳黑及Pt/C催化剂的化学组成、化学状态、晶体结构及表面形貌,并用循环伏安法(CV)测试Pt/C催化剂对甲醇的电催化氧化.结...
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| 关 键 词： | 氧化处理 含氧官能团 锚位 电催化活性 |
The effect of surface chemical state of supports on structure and electrocatalytic activity of Pt/C electrocatalysts |
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| DUAN Jian-jun,LIU Shuo,ZHANG Zheng-fu,SUN Li-jun,YANG Xi-kun,XU Yang-yang,XU Ming-li.The effect of surface chemical state of supports on structure and electrocatalytic activity of Pt/C electrocatalysts[J].Journal of Functional Materials,2011,42(1):83-87. |
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| Authors: | DUAN Jian-jun LIU Shuo ZHANG Zheng-fu SUN Li-jun YANG Xi-kun XU Yang-yang XU Ming-li |
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| Affiliation: | DUAN Jian-jun,LIU Shuo,ZHANG Zheng-fu,SUN Li-jun,YANG Xi-kun,XU Yang-yang,XU Ming-li (Research Center for Analysis and Measurement,Kunming University of Science and Technology,Kunming 650093,China) |
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| Abstract: | A series of carbon black supports with different surface chemical state were prepared with the oxidation treatment of Vulcan XC-72 carbon black.Pt/C catalysts were fabricated with formaldehyde as the reducing agent and hydrochloroplatinic acid as the precursor.The chemical composition,chemical state,crystal structure and surface morphology of carbon black supports and Pt/C catalysts were respectively studied by X-ray photoelectron spectroscopy(XPS),X-ray diffraction(XRD)and transmission electron microscope(... |
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| Keywords: | oxidation treatment oxygen-containing functional group anchor site electrocatalytic activity |
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