| H3O+(H2O)n(n=0～4)与甲醇、乙醇反应的实验研究 |
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| 引用本文： | 李建权,程平,王鸿梅,王占新,储焰南,周士康.H3O+(H2O)n(n=0～4)与甲醇、乙醇反应的实验研究[J].量子电子学报,2004,21(3):302-306. |
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| 作者姓名： | 李建权 程平 王鸿梅 王占新 储焰南 周士康 |
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| 作者单位： | 中国科学院安徽光学精密机械研究所环境光谱学实验室,安徽,合肥,230031 |
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| 基金项目： | 中国科学院合肥物质科学研究院院长基金资助项目 |
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| 摘 要： | 在流动余辉质谱装置上，利用He的空心阴极放电产物与H2O反应制备了反应物离子H3O (H2O)n(n=0～4)，并观察了H3O (H2O)n(n=0～4)与CH3OH、C2H5OH反应的产物离子，对它们进行了归属，分析了各种产物离子形成的离子-分子反应机制。
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| 关 键 词： | 光谱学 流动余辉质谱 甲醇 乙醇 |
| 文章编号： | 1007-5461(2004)03-0302-05 |
| 收稿时间： | 2003/6/2 |
| 修稿时间： | 2003年6月2日 |
Experimental study on reaction of H3O+(H2O)n(n = O～4) with methanol and ethanol |
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| LI Jian-quan,CHENG Ping,WANG Hong-mei,WANG Zhan-xin,CHU Yan-nan ZHOU Shi-kang.Experimental study on reaction of H3O+(H2O)n(n = O～4) with methanol and ethanol[J].Chinese Journal of Quantum Electronics,2004,21(3):302-306. |
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| Authors: | LI Jian-quan CHENG Ping WANG Hong-mei WANG Zhan-xin CHU Yan-nan ZHOU Shi-kang |
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| Abstract: | By the reaction of water vapor with He and He* which were generated by hollow cathode discharge of helium, H3O (H2O)n(n= 0-4) was produced. We studied the reactions of H3O (H2O)n(n= 0-4) with methanol and ethanol in a flowing afterglow mass spectrometer. Various ionic products were identified. They were formed by proton-transfer, ligand switching . association and condensation reactions. |
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| Keywords: | spect roscopy flowing afterglow mass spectrometer methanol ethanol |
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