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Dimensions of the average pore,the number of pores,and the surface area of hardened Portland cement paste
Authors:Raouf Sh. Mikhail  Danica H. Turk  Stephen Brunauer
Affiliation:Institute of Colloid and Surface Science and Department of Chemistry Clarkson College of Technology, Potsdam, N.Y. 13676, USA
Abstract:In the course of their small angle x-ray scattering work, Winslow and Diamond also calculated the radius of gyration of the pores. Using its value for a paste, Diamond adopted two models for the average pore: a sphere and a cylinder of equal height and diameter. This model leads to absurd values for the surface area of the paste. Using a cylindrical model, and the radius of gyration plus the hydraulic radius, the present authors calculated for a similar paste the dimensions of the average pore and obtained the values: diameter = 47.2A?, length = 466A?. The number of pores per gram of paste was 2.26 × 1017. The paper also discusses the surface area of hardened paste, and points out the extremely important contributions of Winslow and Diamond to the subject.
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