| TPPTS柱撑水滑石的制备及表征 |
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| 引用本文： | 卫敏 何静. TPPTS柱撑水滑石的制备及表征[J]. 石油学报(石油加工), 1999, 15(1): 71-74 |
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| 作者姓名： | 卫敏 何静 |
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| 作者单位： | 北京化工大学应用化学系 |
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| 基金项目： | 国家自然科学基金,中国石油化工总公司（X597011）资助 |
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| 摘 要： | 制备了水溶性性好的烯烃氢甲酰化反应催化剂的配体－间三苯基膦三磺酸钠盐，采用＾３１ＰＮＭＲ和ＩＲ对其进行了表征。以层柱化合物类水滑石为插层主体，ＴＰＰＴＳ为插层客体，采用离子交换法和一步合成法制备了ＴＰＰＴＳ柱撑水滑石。
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| 关 键 词： | TPPTS 柱撑水滑石 制备 催化剂 |
PREPARATION AND CHARACTERIZATION OF TPPTS PILLARED HYDROTALCITE |
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| Wei Min He Jing Li Feng D G Evans Duan Xue. PREPARATION AND CHARACTERIZATION OF TPPTS PILLARED HYDROTALCITE[J]. Acta Petrolei Sinica (Petroleum Processing Section), 1999, 15(1): 71-74 |
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| Authors: | Wei Min He Jing Li Feng D G Evans Duan Xue |
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| Abstract: | The ligand of olefin hydroformylation catalyst with excellant solubility in water,namely tris (natrium m sulfonatophenyl) phosphan(TPPTS),was prepared with high pruity and characterized by IR, 31 P NMR and XRD.Layered Double Hydroxides(LDHs)being used as intercalation hosts,and TPPTS as intercalation guest.TPPTS pillared hydrotalcite was prepared by the methods of one step synthesis or ion exchange and could be used as catalyst precursor for olefin hydroformylation.Its IR spectrum exhibits the adsorption peaks of TPPTS and its XRD profile exhibits d 001 betwteen 1 59 and 1 64nm. |
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| Keywords: | TPPTS pillared hydrotalcites preparation characterization |
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