Porous graphite matrix for chemical heat pumps

Expanded graphite powders were prepared by rapid heating of expandable graphite powders intercalated with sulfuric acid at different heat treatment temperatures (HTT). Porous graphite matrices with 100–400 kg m⁻³ of bulk density were fabricated by pressing expanded graphite powders in order to use as heat conductive media. They were characterized using an C/S analyzer, inductively coupled plasma spectroscopy, X-ray diffraction, scanning electron microscopy, Fourier transform infrared (FTIR), nitrogen adsorption, optical microscopy and helium pycnometer before and after heat treatment. Gas permeability and thermal conductivity were measured for porous graphite matrices with different HTT and bulk densities. Chemical analysis and FTIR showed that as the HTT of expandable graphite powders increase, the residual sulfur content decreased remarkably. Nitrogen adsorption experiments for expanded graphite powders showed that specific surface area and total pore volume increased with HTT. Helium penetration results showed that porous graphite matrices with different HTT have noticeably different open porosities which were attributed to the different degrees of expansion of graphite layers. The gas permeability of porous graphite matrices was in the range of 10⁻¹²–10⁻¹⁵ m² and exhibited higher values with low HTT. Thermal conductivity values in the axial and the radial directions were in the range of 4.1–20.0 and 4.6–42.3 W mK⁻¹, respectively. A semi-empirical model was developed that can be used to correlate with the thermal conductivity of graphite matrix on the basis of solid conductivity, bulk density and porosity.