Photochemical behavior of poly(organophosphazenes). X. Photo-cross-linking phenomena in poly[bis(4-isopropylphenoxy)0.8 (4-benzoylphenoxy)1.2 phosphazene] |
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Authors: | Mario Gleria Francesco Minto Lucia Flamigni and Pietro Bortolus |
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Affiliation: | (1) Istituto di Fotochimica e Radiazioni d'Alta Energia del Consiglio Nazionale delle Ricerche Sezione di Legnaro, Via Romea 4, 35020 Legnaro, Padova, Italy;(2) Istituto di Fotochimica e Radiazioni d'Alta Energia del Consiglio Nazionale delle Ricerche, Via De'Castagnoli 1, 40126 Bologna, Italy |
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Abstract: | The synthesis and photochemical behavior both in solution and in the solid state of polybis(4-isopropylphenoxy)0.8 (4-benzoylphenoxy)1.2 phosphazene] is described. The main reaction of this material under illumination with light of a wavelength longer than 340 nm is the intramolecular abstraction of an hydrogen atom by the excited benzophenone substituent from the 4-isopropylphenoxy moiety geminally substituted on the same phosphorus of the phosphazene chain. In this way highly reactive radical species are produced which induce very efficient photo-cross-linking of the phosphazene copolymer and insolubilization. The efficiency of this process in the solid state is examined in view of the potential application of this material as a polyphosphazene-based negative photoresist. |
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Keywords: | Poly[bis(4-isopropylphenoxy)0 8 (4-benzoylphenoxy)1 2 phosphazene] photochemical behavior solution solid state photo-cross-linking |
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