| MEASUREMENT OF EXCESS GIBBS FREE ENERGY MODEL PARAMETERS BY CHROMATOGRAPHIC SLOPE METHOD |
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| 作者姓名： | 徐振林 汪绍昆 田维民 时钧 |
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| 作者单位： | Nanjing Institute of Chemical Technology，Nanjing Institute of Chemical Technology，Nanjing Institute of Chemical Technology，Nanjing Institute of Chemical Technology |
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| 摘 要： | It is found that the expression for(γ/x)_x-o derived on the basis of Lenoir's works should Ix differentfrom that derived by Kikic and Renon in 1976.and(lnγ_1,/x_1)_x_1=0 values have beenmeasured for 10 binary systems by gas-liquid chromatography.According to the new expression,UNIQUACparameters and the vapor-liquid eqilibrium data are evaluated.Of the six systems data available in litera-ture the predicted results are satisfactory.
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| 修稿时间： | |
MEASUREMENT OF EXCESS GIBBS FREE ENERGY MODEL PARAMETERS BY CHROMATOGRAPHIC SLOPE METHOD |
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| XU Zhenlin,WANG Shaokun,TIAN Weimin,SHI Jun.MEASUREMENT OF EXCESS GIBBS FREE ENERGY MODEL PARAMETERS BY CHROMATOGRAPHIC SLOPE METHOD[J].Chinese Journal of Chemical Engineering,1986,1(1):84-94. |
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| Authors: | XU Zhenlin WANG Shaokun TIAN Weimin SHI Jun |
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| Affiliation: | Nanjing Institute of Chemical Technology |
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