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Chemical solution processing and properties of tungsten bronze (ba,la)nb2o6 thin films
Authors:Wataru Sakamoto  Yu Saku Horie  Toshinobu Yogo  Shin Ichi Hirano
Affiliation:Department of Applied Chemistry , Graduate School of Engineering, Nagoya University , Furo-cho, Chikusa-ku, Nagoya, 464-8603, Japan
Abstract:Abstract

Highly oriented (Ba,La)Nb2O6 thin films have been synthesized by a chemical solution deposition method. A homogeneous and stable (Ba0.75La0.167)Nb2O6 (BLN) precursor solution was prepared by controlling the reaction of metal alkoxides. BLN precursor films crystallized in the tetragonal tungsten bronze phase at 700°C. BLN thin films on MgO(100) and Pt(100)/MgO(100) substrates showed the prominent c-axis preferred orientation. BLN thin films on Pt(100)/MgO(100) exhibited the diffuse phase transition depending upon the frequency.
Keywords:(Ba  La)Nb2O6  tungsten bronze structure  thin film  preferred orientation  chemical solution deposition  diffuse phase transition
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