Chemical solution processing and properties of tungsten bronze (ba,la)nb2o6 thin films |
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Authors: | Wataru Sakamoto Yu Saku Horie Toshinobu Yogo Shin Ichi Hirano |
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Affiliation: | Department of Applied Chemistry , Graduate School of Engineering, Nagoya University , Furo-cho, Chikusa-ku, Nagoya, 464-8603, Japan |
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Abstract: | Abstract Highly oriented (Ba,La)Nb2O6 thin films have been synthesized by a chemical solution deposition method. A homogeneous and stable (Ba0.75La0.167)Nb2O6 (BLN) precursor solution was prepared by controlling the reaction of metal alkoxides. BLN precursor films crystallized in the tetragonal tungsten bronze phase at 700°C. BLN thin films on MgO(100) and Pt(100)/MgO(100) substrates showed the prominent c-axis preferred orientation. BLN thin films on Pt(100)/MgO(100) exhibited the diffuse phase transition depending upon the frequency. |
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Keywords: | (Ba La)Nb2O6 tungsten bronze structure thin film preferred orientation chemical solution deposition diffuse phase transition |
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