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四氢萘在国产催化剂上加氢裂化反应网络的研究
引用本文:邱建国,袁兴东,曹祖宾,顾群. 四氢萘在国产催化剂上加氢裂化反应网络的研究[J]. 辽宁石油化工大学学报, 1992, 0(1)
作者姓名:邱建国  袁兴东  曹祖宾  顾群
作者单位:抚顺石油学院,抚顺石油学院,抚顺石油学院,抚顺石油化工研究院
摘    要:
在活性趋于稳定的以改性Y沸石为担体的钼镍催化剂上,利用经改造的国产WF—8900型连续流动微反-色谱装置,进行了四氢萘加氢裂化反应动力学方面的研究。考察其反应产物分布,计算反应网络中各步的反应速度常数和热力学平衡常数,探讨反应网络的主线和反应条件对主线的影响。并探讨了双环裂解深度对单环收率的影响,为加氢裂化技术的发展,提供了一些基础的信息。

关 键 词:加氢裂化  四氢萘  沸石  反应网络

Hydrocracking Network of Tetralin on Supported Molyblenum—Nickel on Modified Zeolite Y Catalysts
Qiu Jianguo Yuan Xingdong Cao Zubin. Hydrocracking Network of Tetralin on Supported Molyblenum—Nickel on Modified Zeolite Y Catalysts[J]. Journal of Liaoning University of Petroleum & Chemical Technology, 1992, 0(1)
Authors:Qiu Jianguo Yuan Xingdong Cao Zubin
Affiliation:Qiu Jianguo Yuan Xingdong Cao Zubin (Fushun Petroleum Institute) Gu Qun (Fushun Reseadi Instiute of Petroleum and Petrochemicals)
Abstract:
The investigation of reaction kineties of tetralin hydrocraking on modified Molyblenum-Nickel catalysts with zeolite Y were conducted in the improved China-made continuous micro reactoe WF-8900 connected with gas chromatograph on-line. Reaction rate constants were calculated upon the products distribution. The main reaction path was given out and the effects of reaction conditions on it were investigated. The effects of two-ring cracking depth on single ring yield were also studied.
Keywords:Hydrocracking  Tetralin  Zeolite  Reaction netmork
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