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磁控溅射Ti合金薄膜结构特征及贮氢性能
引用本文:马爱华,郑华,刘实,王隆保. 磁控溅射Ti合金薄膜结构特征及贮氢性能[J]. 材料研究学报, 2005, 19(1): 64-71
作者姓名:马爱华  郑华  刘实  王隆保
作者单位:中国科学院金属研究所
摘    要:采用磁控溅射方法制备了Ti膜及TiMo、TiMoYAl和TiZrYAl等三种合金膜.合金膜中Mo、Zr和Al三种元素成份与靶材成分基本一致,而Y元素则与靶材成分有较大的偏差.在400℃吸氢工艺下,四种膜材的吸氢动力学性能良好,没有脱膜现象,饱和吸氢量均可超过1.5(H/M).膜材的吸氢PCT曲线表明,含Mo合金膜材具有最高的吸氢平衡压,外推出的室温下的数量级约为10-4Pa.

关 键 词:金属材料  磁控溅射  Ti合金薄膜  贮氢  磁控溅射  合金薄膜  结构特征  贮氢性能  films  alloy  magnetron sputtering  storage characteristic  hydrogen  室温  外推  吸氢平衡压  曲线  饱和吸氢量  现象  脱膜  吸氢动力学性能  膜材  工艺  偏差
文章编号:1005-3093(2005)01-0064-08
收稿时间:2004-04-15
修稿时间:2004-04-15

The structure and hydrogen storage characteristic of magnetron sputtering Ti--base alloy films
MA Aihua,ZHENG Hua,LIU Shi,WANG Longbao. The structure and hydrogen storage characteristic of magnetron sputtering Ti--base alloy films[J]. Chinese Journal of Materials Research, 2005, 19(1): 64-71
Authors:MA Aihua  ZHENG Hua  LIU Shi  WANG Longbao
Abstract:The magnetron sputtering method was used to prepare Ti-base alloy films. The concentration of the alloy elements such as Mo, Zr and Al in the films is consistent with that in the targets, while the Y concentration has a large deviation from that in the targets. The hydrogen absorption dynamics of the four films at 673 K is fine and the TiZrYAI film has the best hydriding activity. The hydrogen storage capacities of all the four films exceed 1.5 (H/M). The hydrogen absorption P-C isotherms of the films were measured. The films alloying with Mo have the highest hydrogen absorption equilibrium pressure, which is determined as about 10-4 Pa at ambient temperature.
Keywords:metallic materials   magnetron sputtering   Ti alloy film   hydrogen storage
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