High conversion polymerization of α-methylstyrene with maleimide at different monomer-to-monomer ratios in the feed |
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| Authors: | F Ranogajec D D Fleš R Vuković |
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| Affiliation: | (1) Institue  Ruder Bo kovi  , Zagreb, Yogoslavia;(2) Department of General and Inorganic Chemistry, Faculty of Technology, Zagreb, Yugoslavia;(3) NA-Research and Development, Zagreb, Yogoslavia |
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| Abstract: | Summary High conversion polymerization of  -methylstyrene (-MeSt) with maleimide (Ml) was performed in Calvet differential microcalorimeter under different monomer-to-monomer ratios in the feed using AIBN as initiator. From the calorimetric curve it was observed that in the presence of an excess of Ml, alternating copolymer is quantitatively formed prior to the formation of poly (Ml). |
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