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硝酸浓度对橄榄石基活性炭特性的影响(英文)
作者姓名:Nouha Soudani  Souad Souissi-najar  Abdelmottaleb Ouederni
作者单位:National School of Engineers of Gabes, University of Gabes, Gabes 6029, Tunisia
摘    要:In this work we investigated the effect of nitric acid concentration on the pore structure, surface chemistry and liquid phase adsorption of olive stone based activated carbon prepared by mixing process using phosphoric acid and steam as activating agents. Chemicals and textural characterization show that the increase of HNO3 concentration increases considerably the total acidic groups but decreases specific surface area and pore volume. The study of adsorption in aqueous solutions of two organics, phenol and methylene blue, on raw and oxidized activated carbon indicates that the treatment of mixed activated carbon with different concentrations of nitric acid improves the adsorbent capacity for methylene blue at HNO3 concentrations less or equal to 2 mol·L 1, while it has a negative effect on phenol adsorption.

关 键 词:activated  carbon  oxidation  nitric  acid  concentration  surface  characteristics  adsorption  
收稿时间:2012-04-19

Influence of Nitric Acid Concentration on Characteristics of Olive Stone Based Activated Carbon
Nouha Soudani,Souad Souissi-najar,Abdelmottaleb Ouederni.Influence of Nitric Acid Concentration on Characteristics of Olive Stone Based Activated Carbon[J].Chinese Journal of Chemical Engineering,2013,21(12):1425-1430.
Authors:Nouha Soudani  Souad  Souissi-najar Abdelmottaleb  Ouederni
Affiliation:National School of Engineers of Gabes, University of Gabes, Gabes 6029, Tunisia
Abstract:In this work we investigated the effect of nitric acid concentration on the pore structure, surface chemistry and liquid phase adsorption of olive stone based activated carbon prepared by mixing process using phosphoric acid and steam as activating agents. Chemicals and textural characterization show that the increase of HNO3 concentration increases considerably the total acidic groups but decreases specific surface area and pore volume. The study of adsorption in aqueous solutions of two organics, phenol and methylene blue, on raw and oxidized activated carbon indicates that the treatment of mixed activated carbon with different concentrations of nitric acid improves the adsorbent capacity for methylene blue at HNO3 concentrations less or equal to 2 mol·L-1, while it has a negative effect on phenol adsorption.
Keywords:activated carbon  oxidation  nitric acid concentration  surface characteristics  adsorption
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