| 钯催化卤代芳烃的胺化反应研究 |
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| 引用本文： | 刘蒲,李三华,李利民,王向宇,殷元骐,张玉华.钯催化卤代芳烃的胺化反应研究[J].化工中间体导刊,2005(23):22-28. |
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| 作者姓名： | 刘蒲 李三华 李利民 王向宇 殷元骐 张玉华 |
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| 作者单位： | [1]郑州大学化学系,郑州450052 [2]中国科学院兰州化学物理研究所,兰州730000 |
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| 摘 要： | 钯催化卤代芳烃胺化是形成CAr-N的重要方法。配体的发展扩展了底物的适用范围，提高了反应的选择性，实现了廉价易得的氯代芳烃的胺化，弱碱的使用提高了官能团的兼容性，因此Pd催化芳胺化广泛应用于合成芳胺类化合物。本文以卤代芳烃为线索，对钯催化偶联胺化反应的研究进展进行了综述和展望。
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| 关 键 词： | 卤代芳烃 钯 催化 胺化 偶联 |
Progress in Palladium-Catalyzed Amination of Aryl Halides |
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| Authors: | Liu Pu Li Sanhua Li Limin Wang Xiangyu Yin Yuanqi Zhang Yuhua |
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| Affiliation: | Department of Chemistry, Zhengzhou University, Zhengzhou 450052, China; Lanzhou Institute of Chemical Physics. Chinese Academy of Sciences, Lanzhau 730000, China |
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| Abstract: | It is an important method to form CAr -N by palladium-catalyzed amination of aryl halidcs. The development of ligands expands the scope of substrates, improves reaction selectivity and realizes the amination of the cheaper and available aryl chlorides. The application of weak base improves the compatibility of functional groups. Pd-catalyzed amination of aryt halides are used in the synthesis of arylamine. The research progress in palladium catalyzed amination is reviewed and prospected by using aryl halides as clue. |
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| Keywords: | aryl halides palladium catalysis amination cross-coupling |
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